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ChemInform Abstract: Synthesis of Indolizine Derivatives by the Reaction of 2-(2′-Pyridyl)-pyridinium Ylides with Ethylenic Dipolarophiles.

✍ Scribed by Ioan I. Druta; Mioara A. Andrei; Cristian I. Ganj; Pompiliu S. Aburel

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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Abstract

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Cycloaddition Reactions of N-(Cyanomethyl)pyridinium Ylides with 2,2-Dihydropolyfluoroalkanoates. -The ylides (I) and (VI) are reacted with polyfluorinated alkanoates under basic conditions to give the corresponding indolizines bearing both a fluoroalkyl and a cyano group. The 3-substituted ylide (V