Synthesis of (4S,5S)-trans-4-(cyclopentadiene-1-methyl)-5-diphenylphosphine-2,2-dimethyl-1,3-dioxolane and the ferrocene derivative; trans-[Feη-C4H4CH2[CHOC(CH3)2OCH]CH2PPh22]
✍ Scribed by Malcolm L.H. Green; Neil M. Walker
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 223 KB
- Volume
- 344
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
The five-step synthesis of the first transition metal complex CH 2 PPh 2 (9), silylated cyclopentadiene (CH 3 ) 3 SiC 5 (CH 3 ) 4 -CH 2 CH 2 PPh 2 (10) and cyclopentadiene HC 5 (CH 3 ) 4 CH 2 -with the C 5 (CH 3 ) 4 CH 2 CH 2 PPh 2 ligand [η 5 :η 1 -C 5 -(CH 3 ) 4 CH 2 CH 2 PPh 2 ]ZrCl 3 •THF (11),
Tripod ligands / Hindered rotation of vinylidene ligands / CpML 2 chelate ligands / Ruthenium / Carbenes / Carbene-type ligands / Cyclic voltammetry The tripodal ligand [CH 3 C(CH 2 C 5 H 4 )(CH 2 PPh 2 ) 2 ] -reacts C(OMe)Me (8), upon treatment with methanol. The vinylidene species 7 are deprotonat