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Synthesis of (4S,5S)-trans-4-(cyclopentadiene-1-methyl)-5-diphenylphosphine-2,2-dimethyl-1,3-dioxolane and the ferrocene derivative; trans-[Feη-C4H4CH2[CHOC(CH3)2OCH]CH2PPh22]

✍ Scribed by Malcolm L.H. Green; Neil M. Walker


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
223 KB
Volume
344
Category
Article
ISSN
0022-328X

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Tripod ligands / Hindered rotation of vinylidene ligands / CpML 2 chelate ligands / Ruthenium / Carbenes / Carbene-type ligands / Cyclic voltammetry The tripodal ligand [CH 3 C(CH 2 C 5 H 4 )(CH 2 PPh 2 ) 2 ] -reacts C(OMe)Me (8), upon treatment with methanol. The vinylidene species 7 are deprotonat