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Synthesis of (4R,9Z)-9-Octadecen-4-olide, the Female Sex Pheromone of Janus integer, and Its Enantiomer

✍ Scribed by Chié Shibata; Kenji Mori


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
138 KB
Volume
2004
Category
Article
ISSN
1434-193X

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Pheromone Synthesis, CLXXXI. Synthesis o
✍ Nakayama, Tôru ;Mori, Kenji 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 525 KB

## Abstract (4__R__,7__Z__)‐7,15‐Hexadecadien‐4‐olide (1), the female‐produced sex pheromone of the yellowish elongate chafer (__Heptophylla picea__), was synthesized by lipase‐catalyzed resolution of (±)‐10. The racemate and the opposite (__S__)‐enantiomer of the pheromone were also synthesized. B

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## Abstract (4__R__,5__R__,6__S__,7__E__,9__E__)‐4,6,8‐Trimethyl‐7,9‐undecadien‐5‐ol (1) and its antipode 1′, the female specific compound of the woodroach __Cryptocercus punctulatus__, were synthesized by starting from methyl (__R__)‐3‐hydroxy‐2‐methylpropanoate (C).