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Pheromone Synthesis, CLXXXI. Synthesis of the Racemate and the Enantiomers of (Z)-7,15-Hexadecadien-4-olide, the Sex Pheromone of the Yellowish Elongate Chafer,Heptophylla picea

✍ Scribed by Nakayama, Tôru ;Mori, Kenji

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 525 KB
Volume: 1997
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199719970508

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✦ Synopsis

Abstract

(4__R__,7__Z__)‐7,15‐Hexadecadien‐4‐olide (1), the female‐produced sex pheromone of the yellowish elongate chafer (Heptophylla picea), was synthesized by lipase‐catalyzed resolution of (±)‐10. The racemate and the opposite (S)‐enantiomer of the pheromone were also synthesized. Both (R)‐1 and (±)‐1 showed the pheromone activity.

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