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Synthesis of (−)-(4R,5R)- and (+)-(4S,5S)-1-alkyl-4-(4′-nitrophenyl)-1-azonium-3,7-dioxabicyclo[3.3.0]octane halides

✍ Scribed by V. P. Zaitsev; P. P. Purygin; S. Kh. Sharipova


Publisher
Springer US
Year
1990
Tongue
English
Weight
128 KB
Volume
26
Category
Article
ISSN
0009-3122

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## Abstract (2__R__,4__S__,5__S__)‐(+)‐5‐(2,2‐Dichloroacetamido)‐4‐(4‐nitrophenyl)‐2‐aryl‐1,3‐dioxanes **3–8** were synthesized with high diastereoselectivity and good yields. The structures of acetals were determined and the configurations were confirmed by 2D‐NMR (NOESY) and X‐ray crystallographi