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Synthesis of 4H-furo[3,2-b]indoles. II. Bromination, acylation and nitration of 4H- and 4-benzoylfuro[3,2-b]indoles

โœ Scribed by Akira Tanaka; Kenichi Yakushijin; The Late Shigetaka Yoshina


Book ID
112125220
Publisher
Journal of Heterocyclic Chemistry
Year
1978
Tongue
English
Weight
206 KB
Volume
15
Category
Article
ISSN
0022-152X

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4-(phenylsulfonyl)-4H-furo[3,4-b]indole
โœ Mark G. Saulnier; Gordon W. Gribble ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 237 KB

The N-phenylsulfonyl derivative (2) of the previously unknown fused heterocycle 4Hfuro[3,4-blindole is synthesized from indole-3-carboxaldehyde (2) in 28% yield and undergoes a Diels-Alder reaction with benzyne to give 5H-benzo[b]carbazole (11) in -33% yield after deoxygenation and deprotection.