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Synthesis of 4,6-Dinitrobenzo[b]furans from 1,3,5-Trinitrobenzene.

โœ Scribed by Mikhail D. Dutov; Irina A. Vatsadze; Sergei S. Vorob'ev; Svyatoslav A. Shevelev


Publisher
John Wiley and Sons
Year
2006
Weight
21 KB
Volume
37
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reaction of 1,8-Dia
โœ J. K. SUTHERLAND ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 1 views

Reaction of 1,8-Diazabicyclo(5.4.0)undec-8-ene with Methyl 3,5-Dinitrobenzoate and 1,3,5-Trinitrobenzene. -The initial reaction of DBU (II) with title compounds (I) and (V) gives the corresponding Meisenheimer complexes which undergo oxidation and ipso-displacement to form crimson 2-aminoindole der