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ChemInform Abstract: Reaction of 1,8-Diazabicyclo(5.4.0)undec-8-ene with Methyl 3,5- Dinitrobenzoate and 1,3,5-Trinitrobenzene.

✍ Scribed by J. K. SUTHERLAND

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199727172

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✦ Synopsis

Reaction of 1,8-Diazabicyclo(5.4.0)undec-8-ene with Methyl 3,5-Dinitrobenzoate and 1,3,5-Trinitrobenzene.

-The initial reaction of DBU (II) with title compounds (I) and (V) gives the corresponding Meisenheimer complexes which undergo oxidation and ipso-displacement to form crimson 2-aminoindole derivatives (III) and (VI). -(SUTHERLAND, J. K.; Chem. Commun. (Cambridge) (1997) 3,

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