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Synthesis of 4,5-bifunctionally substituted imidazolidin-2-ones

✍ Scribed by A. D. Shutalev

Publisher
Springer US
Year
1993
Tongue
English
Weight
414 KB
Volume
29
Category
Article
ISSN
0009-3122

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✍ Lianyun Zhao; Lixin Qiao; Suo-Bao Rong; Alan P Kozikowski πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 133 KB

The total synthesis of substituted (4S)-4-(hydroxymethyl)imidazolidin-2-ones from D-serine methyl ester is described. The key step in the synthesis is a reductive amination reaction which is brought about using titanium(IV) isopropoxide and sodium cyanoborohydride, followed by the cyclization to ure