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Synthesis of 4,4-Diphenyl-1-methylpiperidine 1

โœ Scribed by Sperber, Nathan; Sherlock, Margaret; Papa, Domenick


Book ID
127188425
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
514 KB
Volume
75
Category
Article
ISSN
0002-7863

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trans-1,4-Diphenyl-1,4-diphosphacyclohex
โœ Williams, Michael L. ;Dunstan, Samuel P. C. ;Healy, Peter C. ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 733 KB

The molecule of the title compound, C~16~H~18~P~2~, which was prepared by the reaction of dichloroethane with lithiated bis(diphenylphosphino)ethane, is disposed about a centre of symmetry. The 1,4-diphosphacyclohexane ring adopts a chair conformation with axial phenyl groups. The planes of the phen