Synthesis of 4,4-bis(2-hydroperoxyalkyl)
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Md.Taifur Rahman; Hiroshi Nishino; Chang-Yi Qian
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Article
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2003
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Elsevier Science
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French
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The autoxidation of a mixture of 1,2-disubstituted pyrazolidine-3,5-diones 1 and alkenes 2 in the presence of a catalytic amount of manganese(III) acetate dihydrate in air gave 4,4-bis(2-hydroperoxyalkyl)pyrazolidine-3,5-diones 3 in 75-96% yields. The structure of the bis(2-hydroperoxyethyl)pyrazoli