Synthesis of 4'-vinyl-2,2':6',2''-terpyridine
✍ Scribed by Potts, Kevin T.; Konwar, Dilip
- Book ID
- 120822409
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 271 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title molecule, C~22~H~17~N~3~O, the three pyridyl rings are almost coplanar. The molecule exhibits a __trans__–__trans__ arrangement of the pyridine rings about the interannular C—C bonds. The methoxyphenyl substituent makes a dihedral angle of 6.17 (7)° with the central pyridine ring.
The complex [Pt(Cl 3 terpy)Cl]PF 6 has been prepared from cis-[Pt(dimethylsulfoxide) 2 Cl 2 ] and 4,4%,4¦-trichloro-2,2%:6%,2¦-terpyridine (Cl 3 terpy). The complex [Pt(Clterpy)Cl]Cl has been prepared from cis-[Pt (1,5-cyclooctadiene)Cl 2 ] and 4%-chloro-2,2%:6%,2¦terpyridine (Clterpy). Complexes ha