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Synthesis of 4-O-β-d-galactopyranosyl-3-O-methyl-d-glucose

✍ Scribed by James Hoffman; Olof Theander; Mats Lindberg; Thomas Norberg


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
322 KB
Volume
137
Category
Article
ISSN
0008-6215

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Halide-assisted glycosyIation, using a non-p~icipating Z-substituent (benzyl) in the glycosyl halide, was used to obtain the ~-D-gaiactosyl linkage and silver triflate promotion with a participating 2-substituent (benzoyl) was used to obtain the /3-D-galactosyl linkage in a facile synthesis of the t