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Synthesis of 4-(N,N-Dialkylamino)benzyltriphenylphosphonium Iodides from Hydroxymethyltriphenylphosphonium Iodide and N,N-Dialkylaniline

โœ Scribed by Davis, Matthew C.; Parrish, Damon A.


Book ID
115538570
Publisher
Taylor and Francis Group
Year
2008
Tongue
English
Weight
186 KB
Volume
38
Category
Article
ISSN
0039-7911

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Synthesis of 2,5-bis(N,N-dialkylamino)th
โœ Olga A. Tarasova; Nina A. Nedolya; Vladimir Yu. Vvedensky; Lambert Brandsma; Bor ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 89 KB

A bs trac t: Reaction of lithiated ptopargylic amines with isothiocyanates, followed by addition of t-BuOK, t-BuOH and methyl iodide gives either 2,5-bis(N,N-dialkylamino)thiophenes or 1-alkyl-2-N,N-dialkylamino-5-methylthiopyn'oles depending on the temperature during the treatment with the base.