Synthesis of 3α-hydroxy-6-ketobrassinosteroids
✍ Scribed by N. V. Kovganko; O. P. Kananovich; S. K. Ananich
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 410 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0009-3130
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We report on the conversion of cholesterol to A=\*7 -cholestadien-la,3g-diol diacetate (6) the photoprecursor of the physiologically active la-hydroxyvitamin D3,1 via A6-cholesten-la.Sg-diol @a). The latter compound was synthesized by modification of a recently published procedure of Li/liquid NH3 r
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