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Synthesis of 35S- and 14C-labeled glyceryl thioethers

✍ Scribed by Claude Piantadost; Fred Snyder; Randall Wood


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
209 KB
Volume
58
Category
Article
ISSN
0022-3549

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πŸ“œ SIMILAR VOLUMES


Synthesis of 14C and 35S labelled carbon
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## Abstract Carbonyl sulfide (COS) was prepared by a replacement reaction from potassium thiocyanate (KSCN) in 50% sulfuric acid. ^14^C‐COS or ^35^S‐COS can be prepared by the same method, depending on the position of the label in the starting KSCN. The yield of the final product is in excess of 60

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Und yl, dodecyl and hexadecyl sulphonates were prepared w i t h y&-label i n t h e 1 -p o s i t i o n . The syntheses r e q u i r e t h e f o r m a t i o n o f a Grignard intermediate from t h e appropriate n-1 a l k y l bromide f o l l o w e d by c a r b o x y l a t i o n o f t h e Grignard w i t h

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