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Synthesis of 3,5-Dihydroxy-2-Methyl-5,6-Dihydropyran-4-one from Aldohexoses and Secondary Amine salts

โœ Scribed by G. A. M. van den Ouweland; H. G. Peer


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
243 KB
Volume
89
Category
Article
ISSN
0165-0513

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6-Methyl-3-benzylidene-5,6-dihydropyran-
โœ Masayuki Sato; Satoshi Sunami; Chikara Kaneko; Shun-ichi Satoh; Toshio Furuya ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 293 KB

S)-6-Methyl-Q-3-benzylidene-5,6-dihydropyran-2,4-diones have been synthesized from (S)-6-methyl-5.6-dihydropyran-2,4-dione through Knoevenagel condensation with an arylaldehyde followed by recrystallization from ether. The results of conjugate additions and hetero Diels-Alder reactions of these comp