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Synthesis of 3,4-fused cycloalkanopyrroles by 1,3-dipolar cycloaddition

✍ Scribed by James M. Kelly; Finian J. Leeper

Book ID
113930373
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
882 KB
Volume
53
Category
Article
ISSN
0040-4039

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## Abstract The reaction of N‐aryl‐C‐ethoxycarbonyl nitrilimines with [1,2,4]triazepin‐3,5‐dithione leads to title compounds. The 1,3‐dipolar cycloaddition is completely peri and regioselective. The preferred orientation of addition is predicted correctly by AM~1~ calculation.