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Synthesis of 3-Oxoalkylphosphonates via the Conjugate Addition of Acylcuprates to Diethyl Vinylphosphonate

✍ Scribed by Li, Nan-Sheng; Yu, Su; Kabalka, George W.

Book ID
120921752
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
99 KB
Volume
18
Category
Article
ISSN
0276-7333

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ChemInform Abstract: Synthesis of 3-Oxoalkylphosphonates via the Conjugate Addition of Acylcuprates to Diethyl Vinylphosphonate.
✍ Nan-Sheng Li; Su Yu; George W. Kabalka πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 1 views

Synthesis of 3-Oxoalkylphosphonates via the Conjugate Addition of Acylcuprates to Diethyl Vinylphosphonate. -Acylcuprates, generated in situ from dialkylcyanocuprates (I) and carbon monoxide, are added to vinylphosphonate (III) to give, after hydrolysis, phosphonates (IV) in good yields. Phosphonat