The reactions of 0, with ethylene, allene, 1,3-butadiene, and trans-1,3-pentadiene have been studied in the presence of excess 0, over the temperature range 232 to 298 K. The initial 0, pressure was varied from 4-18 mtorr, and the olefin pressure was varied from 0.1 to 4.5 torr (ethylene), 2.8 to 39
β¦ LIBER β¦
Synthesis of 3-methyl-1,3-pentadiene by the codimerization of 1,3-butadiene with ethylene
β Scribed by A. B. Amerik; V. M. Vdovin; V. A. Poletaev
- Book ID
- 118288864
- Publisher
- Springer
- Year
- 1977
- Tongue
- English
- Weight
- 271 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1573-9171
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## Abstract 3βMethylβ1,3βpentadiene has been polymerized with the Al(C~2~H~5~)~2~Cl/Nd(OCOC~7~H~15~)~3~/Al[CH~2~CH(CH~3~)~2~]~3~ system to crystalline polymers consisting essentially of cisβ1,4 units (β₯80%). NMR examination has shown that the polymers have an isotactic structure. This conclusion wa