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Synthesis of 3′-(L-2-amino-3-phenylpropyl)amino-3′-deoxy-N6,N6-dimethyladenosine - a new analog of puromycin

✍ Scribed by Tetsuo Kato; Jiří Žemlička

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
212 KB
Volume
19
Category
Article
ISSN
0040-4039

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Dedicated to Professor Hitosi Nozaki on the occasion of his 60th birthday. Magnesium enolates of t-butyl (or ethyl) acetate and t-butyl propionate are found to react with nitriles to give 3-amino-2-alkenoates having Z configuration. The title compounds are versatile intermediates for the synthesis