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SYNTHESIS OF 2(N-ALKYLAMINO)ISOBUTYRALDEHYDES

โœ Scribed by De Kimpe, Norbert; Boeykens, Marc; Boelens, Mark; Buck, Kurt De; Cornelis, Johan

Book ID
125833071
Publisher
Taylor and Francis Group
Year
1992
Tongue
English
Weight
199 KB
Volume
24
Category
Article
ISSN
0030-4948

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Synthesis of 2-(alkylamino)benzimidazole
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โœ James J. Perkins; Amy E. Zartman; Robert S. Meissner ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

A general and highly convenient procedure for the synthesis of 2-(alkylamino)benzimidazoles has been developed and a variety of analogs have been efficiently prepared. Included is a dipeptide mimetic in which the guanidine group of an arginine residue has been replaced with a 2-aminobenzimidazole.

ChemInform Abstract: Synthesis of 2-(Alk
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Synthesis of 2-(Alkylamino)benzimidazoles. -Reaction of an alkylamine and a 1,2-phenylenediamine with thiocarbonyldiimidazole (I) forms the corresponding mixed thioureas, e.g. (IV). These undergo cyclodesulfurization to produce the title compounds. -(PERKINS,