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Synthesis of [2H]-diethoxymethane as a convenient source of a [2H]-methylene unit

✍ Scribed by John A. Hanley; David A. Forsyth

Publisher
John Wiley and Sons
Year
1990
Tongue
French
Weight
187 KB
Volume
28
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

[^2^H]‐Diethoxymethane is prepared in one step from triethylorthoformate. Its usefulness as a precursor to [^2^H]‐formaldehyde is shown by the Diels Alder synthesis of a monolabelled bicyclic amine. The title compound should also be useful in the syntheses of other labelled compounds in which [^2^H]‐formaldehyde is a required reagent.

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## Triethoxy-deuteriomethane i s s y n t h e s i z e d s i m p l y f r o m d e u t e r i oc h l o r o f o r m and m o n o d e u t e r i o -e t h a n o l . The p r e v i o u s l y n o t d e s c r i b e d e t h o x y -[ H j m e t h y l e n e m a l o n o n i t r i l e c a n be p r e p a r e d f r o m