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Synthesis of 2,5-furandicarboxylic acid by the aerobic oxidation of 5-hydroxymethyl furfural over supported metal catalysts

✍ Scribed by Sahu, Ramakanta; Dhepe, Paresh L.

Book ID
125368258
Publisher
Springer-Verlag
Year
2014
Tongue
English
Weight
506 KB
Volume
112
Category
Article
ISSN
1878-5190

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## Abstract __5‐hydroxymethyl‐2‐furfural is selectively converted into 2,5‐furandicarboxylic acid (99β€…mol % yield) in water, under mild conditions (65–130 °C, 10β€…bar air) with gold nanoparticles supported on nanoparticulate ceria (Au‐CeO~2~) and on titania (Au‐TiO~2~); the former being more active

On the mechanism of selective oxidation
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✍ Davis, Sara E. ;Zope, Bhushan N. ;Davis, Robert J. πŸ“‚ Article πŸ“… 2012 πŸ› Royal Society of Chemistry 🌐 English βš– 411 KB

The mechanism of selective oxidation of aqueous 5-hydroxymethylfurfural (HMF) at high pH was studied over supported Pt and Au catalysts. Results from labeling experiments conducted with 18 O 2 and H 2 18 O indicated that water was the source of oxygen atoms during the oxidation of HMF to 2-hydroxyme