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On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts

✍ Scribed by Davis, Sara E. ;Zope, Bhushan N. ;Davis, Robert J.

Book ID
120071082
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
411 KB
Volume
14
Category
Article
ISSN
1463-9262

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On the mechanism of selective oxidation
On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts
✍ Davis, Sara E. ;Zope, Bhushan N. ;Davis, Robert J. πŸ“‚ Article πŸ“… 2012 πŸ› Royal Society of Chemistry 🌐 English βš– 411 KB

The mechanism of selective oxidation of aqueous 5-hydroxymethylfurfural (HMF) at high pH was studied over supported Pt and Au catalysts. Results from labeling experiments conducted with 18 O 2 and H 2 18 O indicated that water was the source of oxygen atoms during the oxidation of HMF to 2-hydroxyme

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The structure–activity relationship and reaction mechanism for selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) in toluene were studied on vanadium oxide domains on TiO~2~, Al~2~O~3~, Nb~2~O~5~, ZrO~2~, and MgO and with a wide range of VO~__x__~ surface densities. The