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Synthesis of 2,4-diphenyl-5-ethoxycarbonyl-1-heptadeuterated isopropyl-2-imidazoline

✍ Scribed by M. Bonnier; A. Marsura; C. Luu-Duc

Book ID
102373622
Publisher
John Wiley and Sons
Year
1986
Tongue
French
Weight
179 KB
Volume
23
Category
Article
ISSN
0022-2135

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✦ Synopsis

The synthesis of the title compound is described from heptadeuterated isopropyl alcohol in six steps. Overall yield obtained was 6%.

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The title compound, C~25~H~29~NO~3~, was prepared in the course of the generation of depsipeptide libraries resembling the Jasplakinolide family of natural products. The dihedral angle between the phenyl ring planes is 74.1β€…(3)Β° The oxazolidinone ring adopts a slightly distorted ^4^ __E__ conformati