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Synthesis of 2,4-Dinitrophenyl α- and β-O-Glycosides

✍ Scribed by Dipl.-Chem. W. Hengstenberg; Prof. Dr. K. Wallenfels


Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
124 KB
Volume
4
Category
Article
ISSN
0044-8249

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A chemoenzymatic synthesis of the O-glyc
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Almond ␤-glucosidase was used to catalyze the synthesis of alkyl ␤-Dglucopyranosides 1b-3b starting from either D-glucose (4) or phenyl-␤-Dglucopyranoside (5) and the racemic alcohols 1a-3a. The enzymic reactions were provided in different acetonitrile/water mixtures [9:1 (v/v) for the reverse hydro