Synthesis of 2,4-bis (imino) azetidines
✍ Scribed by Gerrit L'abbé; Dominique Sorgeloos; Suzanne Toppet
- Book ID
- 104221764
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 357 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The reactions of carbodiimides with N-sulfonyl substituted ketenimines and those of bis(imino)thiazetidines with ester phosphoranes yield 2,4-bis(imino)azetidines. The limitations of the methods are outlined. Four-membered ring amidines' (imino analogues of B-lactams), as well as the corresponding imminium salts, 2 and 4-iminoazetidin-2-ones 334 are of current interest. For bis(imino)azetidines
📜 SIMILAR VOLUMES
Chiral C 2 -symmetric N-benzylazetidines have been conveniently prepared from optically pure anti-1,3-diols without loss of enantiomeric purity. N-Debenzylation led to the corresponding N-unsubstituted azetidines, which were then subjected to palladium-catalysed coupling reactions with aryl [a]