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Synthesis of [2,3,4,5,6-2H5]phenyl glucosinolate

✍ Scribed by Jason B. Bialecki; Josef Ruzicka; Athula B. Attygalle

Publisher
John Wiley and Sons
Year
2007
Tongue
French
Weight
248 KB
Volume
50
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Starting from commercially available [2,3,4,5,6‐^2^H~5~]benzoic acid, [2,3,4,5,6‐^2^H~5~]phenyl glucosinolate was synthesized. Under negative‐ion electrospray‐ionization mass spectrometric conditions, this compound affords a peak at m/z 399. Since this m/z value is not known from the ions derived from natural glucosinolates, the [2,3,4,5,6‐^2^H~5~]phenyl glucosinolate reported here is useful as an internal standard for the quantification of glucosinolates by negative‐ion mass spectrometry (MS) and liquid chromatography (LC)/MS techniques. Copyright © 2007 John Wiley & Sons, Ltd.

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