Pyridine-based mono(ligand)nickel(0) com
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Uwe Rosenthal; Siegmar Pulst; Rhett Kempe; Klaus-Richard PΓΆrschke; Richard Godda
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Article
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1998
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Elsevier Science
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French
β 627 KB
The reaction of rac./meso-(la-~2,112-C.THl2){Ni(1]2,~2-C7Hl2)}2 with 2,6-dimethylpyridine (Me2py) affords (Me2py)Ni0q2,rl2-C7I~12) (1). Complex 1 serves as precursor for the preparation of the Ni(0)-bis(alkyne) complexes (Me2py)Ni012-PhC~SiMe3)2 (2) and {(Me2py)Ni}2(la-rl2,rl2-Me3SiC~--C-C-=CSiMe3)2