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Synthesis of 2-substituted pyridines catalyzed by cobalt(I) complexes and promoted by light

✍ Scribed by Barbara Heller; Jonathan Reihsig; Wolfgang Schulz; Günther Oehme


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
339 KB
Volume
7
Category
Article
ISSN
0268-2605

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## Organorhodium complexes, such as RhH(PPh 3 ) 4 , RhH(CO)(PPh 3 ) 3 , Rh( 3 -C 3 H 4 Ph)(CO)(PPh 3 ) 2 , and RhH(dppe) 2 [dppe = 1,2 -bis(diphenylphosphinoethane)], catalyze polymerization of phenylallene and of 4-methylphenylallene at 60 °C. High-molecular-weight polymers (M n > 4ϫ 10 5 ) are i