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Synthesis of 2-substituted morpholines from dihydroxyalkylsulfamates

✍ Scribed by P. V. Bulatov; A. S. Ermakov; V. A. Tartakovsky

Publisher
Springer
Year
1999
Tongue
English
Weight
199 KB
Volume
48
Category
Article
ISSN
1573-9171

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## Abstract The synthesis of morpholines and oxazepanes derivatives containing a trifluoromethyl group on a quaternary carbon has been achieved from a common enantiopure __O__‐allyl amino ether precursor. Classic 6‐__exo__ iodoamination provided the iodomorpholines, versatile synthetic intermediate