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Synthesis of 2-oxiranyl and aziridinyl thiazoles

✍ Scribed by Saverio Florio; Luigino Troisi; Vito Capriati

Book ID
104260006
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
281 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

2-Oxiranyl and 2-aziridinyl thiazoles 3 and 7 have been prepared by lithiation of thiazoles la and lb and reaction with ct-halogenocarbonyl compounds [1 a, lc-d] and ct-halogenoimines [1 b], respectively.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Synthesis of 2-Oxir
ChemInform Abstract: Synthesis of 2-Oxiranyl and Aziridinyl Thiazoles.
✍ S. FLORIO; L. TROISI; V. CAPRIATI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

Synthesis of 2-Oxiranyl and Aziridinyl Thiazoles. -Lithiation of thiazoles (I) and (XVI) and subsequent reaction of the resulting 2-lithiothiazole intermediates with Ξ±-halogenocarbonyl compounds or Ξ±-halogenoimines provides a convenient access to 2-oxiranyl and aziridinyl thiazoles. However, no suc