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Synthesis of 2-methyl-6,7-benzomorphane via radical cyclisation

✍ Scribed by Lucien Stella; Bernard Raynier; Jean-Marie Surzur

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
191 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

Synthesis of compounds structurally related to morphine is a field of lasting interest to many chemists. These substances form a well-known class of analgesics2 which can possess properties of antagonism to narcotics3 and which includes phenazocine4 and pentazocine5 of medicinal use. The Grewe synthesis6 has been extended to.the preparation of a number

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Synthesis of propellanes via the intramo
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The Michael type addition of vinyl radicals on to the enone double bond was realised in Wieland-Miescher ketone derivatives leading to the formation of functionalised propellanes.