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Synthesis of 2-diethylaminothiocarbonylthio-5,5-dimethylcyclohexane-1,3-dione by cleavage of a phenyliodonium betaine and preparation of a new type of tetrathiafulvalene from it

✍ Scribed by O. Ya. Neiland; B. Ya. Adamsone


Book ID
104781451
Publisher
Springer US
Year
1991
Tongue
English
Weight
168 KB
Volume
27
Category
Article
ISSN
0009-3122

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Tic palladium-catalyzed intramolecular cyclization of l-butyl-l(o-iodobenzyl)-3-pheaylurea 1 at gOΒ°C m the Ixesence of carbon monoxide at atmospheric pressure gives the corresl~nding 2,3,4,5-teWahydro-IH-2,4benzodiazepine-1,3-dione derivative 2 in 91% yield. Yield and selectivity are strongly affect