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Synthesis of 2-Deoxy-2- C -alkyl Glycal and Glycopyranosides from 2-Hydroxy Glycal Ester

✍ Scribed by Daskhan, Gour Chand; Jayaraman, Narayanaswamy


Book ID
118140923
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
386 KB
Volume
77
Category
Article
ISSN
0022-3263

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Under microwave irradiation, perbenzylated pyranoid glycals were coupled with aryl bromides in the presence of 5% mol palladium(II) acetate in dimethylformamide to produce 2 0 ,3 0 -unsaturated C-aryl-aglycopyranosides in a rapid and stereospecific manner. The synthetic applicability of the method w