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Synthesis of phenyl 2-azido-2-deoxy-1-selenoglycosides from disaccharidic glycals

✍ Scribed by Francisco Santoyo-González; Francisco G. Calvo-Flores; Pilar García-Mendoza; Fernando Hernández-Mateo; Joaquín Isac-García; Rafael Robles-Díaz


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
206 KB
Volume
260
Category
Article
ISSN
0008-6215

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Synthesis of 2′-deoxy-2′-phenylselenenyl
✍ Yolanda Díaz; Anas El-Laghdach; Sergio Castillón 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 1020 KB

2'-Deoxy-2'-phenylselenenyl-furanosyl nucleosides have been synthesized stereoselectively from glycals using selenium reagents, and converted into 2'-deoxynucleosides by treatment with tributyltin hydride. Some of the factors which affect the stereoselectivity of the reaction are the stereochemistry