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Synthesis of 2-benzamido-2-mercaptopropanoic acid

✍ Scribed by Peter M. Pojer; Ian D. Rae


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
130 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


The epidithiopiperazine dione ring system (I) is common to a small group of fungal metabolites which are among the most virulent of poisons.


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1-Benzamido-2-(2-furyl)-3-phenylcyclopro
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The molecule of the title compound, C 21 H 17 NO 4 , exhibits a trans arrangement of the furyl and phenyl substituents on the cyclopropane ring. The crystal structure is stabilized by intermolecular O-HÁ Á ÁO hydrogen-bond interactions.

Synthesis and crystal structure investig
✍ R. Ramasubramanian; S. Kumaresan; R. Thomas; A. David Stephen; P. Kumaradhas πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 190 KB

## Abstract Pyridine‐2‐(3′‐mercaptopropanoic acid)‐__N__ ‐oxide (I), is a higher homologue of 1‐oxopyridinium‐2‐thioacetic acid (II) [1]. It crystallizes in monoclinic space group P2~1~ with a = 9.2168(2) Γ…, b = 4.1423(2) Γ…, c = 11.3904(4) Γ…, Ξ² = 98.65(2)Β°, V = 429.93(3) Γ…^3^ and Z = 2. The least‐s