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Synthesis Of 2-Aryl- and 2-Vinyl-1H-indoles via Palladium-Catalyzed Cross-Coupling of Aryl and Vinyl Halides with 1-Carboxy-2-(tributylstannyl)indole

โœ Scribed by Hudkins, Robert L.; Diebold, James L.; Marsh, Frank D.


Book ID
124161861
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
371 KB
Volume
60
Category
Article
ISSN
0022-3263

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Palladium/copper (I) halide catalyzed cross couplings of (E)-and (Z)-I,2difluorovinyistannanes with aryl iodides and vinyl halides proceeded at room temperature to stereospecifically give 1,2-disubstituted-l,2-difluoroolef'ms and 1,2difluoro or 1,2,3,4-tetrafluorosubstituted dienes in good to excell