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Synthesis of 2-[(3-aminoalkyl or 3-bromoalkyl)amino]-4H-1-benzopyran-4-one derivatives
β Scribed by Enzo Sottofattori; Teresa Grandi; Alessandro Balbi
- Book ID
- 103402191
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 130 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
## Abstract magnified image The title aldehyde **1** reacts smoothly with the enamine moiety of **2**βaminochromone **2** to produce hitherto unreported 3β(2βhydroxybenzoyl)β5__H__β1βbenzopyrano[2,3β__b__]pyridinβ5βone (azaxanthone) **5**. This reaction has been extended for the synthesis of bisaz
Highly enantioselective reduction of 3,4-dihydro-2,2-dimethyl-2H-l-benzopyran-4-ones 3 s-e by BH3 was achieved in the presence of catalytic amounts of Corey's oxazaborolidine 4 to afford the corresponding 3,4-dihydro-2,2dimetbyl-2H-l-~nzopyran-4-ols 2a-e in quantitative yields. These benzopyran-4-ol