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Reactions of 2-amino-4h-1-benzopyran-4-one with 4-oxo-4h-1-benzopyran-3-carbaldehydes
โ Scribed by Tarun Ghosh; Chandrakanta Bandyopadhyay
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2006
- Tongue
- English
- Weight
- 267 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-152X
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โฆ Synopsis
Abstract
magnified image
The title aldehyde 1 reacts smoothly with the enamine moiety of 2โaminochromone 2 to produce hitherto unreported 3โ(2โhydroxybenzoyl)โ5__H__โ1โbenzopyrano[2,3โb]pyridinโ5โone (azaxanthone) 5. This reaction has been extended for the synthesis of bisazaxanthone 9.
๐ SIMILAR VOLUMES
## Abstract The title aldehyde 1 in the presence of ammonia gives the pyridine derivatives 9โ11 respectively with acetylacetone, diethyl malonate and ethyl cyanoacetate, and ethyl (or methyl)โlโbenzopyrano[4,3โ__b__]pyriโdineโ3โcarboxylate **22** (or **23**) with ethyl (or methyl) acetoacetate. Ace