a-MrltratnatinI~1~~~~~\_)-2,4di~yl-5sthyla,8dioxabicyclo I3.2.lloctanal was syntheszzed from @)-2-butene-1,4-diol monobenzyl ether by employing the Sharpless aeymmetrlc epoxldatlon and the regloeelective epoxide cleavage with Me3Al as the key-steps. The smaller European elm bark beetle, Scolytus mu
✦ LIBER ✦
Synthesis of (1S:2R:4S:5R)-(−)-α-multistriatin : The pheromone in the smaller European elm bark beetle, scolytus multistriatus
✍ Scribed by K. Mori
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 394 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4020
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## Abstract (−)‐Bicolorin [(1__S__,2__R__,5__R__)‐(−)‐2‐ethyl‐1,5‐dimethyl‐6,8‐dioxabicyclo[3.2.1]octane (1)], the male‐produced pheromone of __Taphrorychus bicolor__, and its (1__R__,2__R__,5__S__) isomer 2 were synthesized by starting from (__S__)‐limonene oxide (3), employing osmium tetroxide ca
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