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Synthesis of 1,9-Disubstituted Phenalenes and their Structural Assignment by HMQC and HMBC Experiments

✍ Scribed by B. Meltzheim; B. Waegell; R. Faure; L. Germanaud; F. Tort

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 430 KB
Volume: 34
Category: Article
ISSN: 0749-1581
DOI: 10.1002/(sici)1097-458x(199605)34:5<383::aid-omr881>3.0.co;2-b

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✦ Synopsis

The reaction of phenalenone with various sulphur-derived nucleophiles gave 1-hydroxy-Palkyl-or -arylthiophenalenes. The complexity of the aromatic 'H and I3C signals does not allow straightforward assignments. These were rendered possible by the use of two-dimensional 'H-detected heteronuclear one-bond (HMQC) and multiple-bond (HMBC) correlation techniques.

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