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Synthesis of 1,8-naphthylene-bridged syn-cyclophanes by efficient intramolecular [2 + 2] photocycloaddition

✍ Scribed by Yosuke Nakamura; Miho Matsumoto; Yoshitou Hayashida; Jun Nishimura

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 217 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00254-2

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✦ Synopsis

Novel 1,8-naphthylene-bridged paraand metacyclophanes were efficiently synthesized as a single isomer by the intramolecular [2 + 21 photocycloaddition of 1,8-bis(p-and m-vinylphenyl)naphthalenes, respectively. By this method, syn-cyclophanes were selectively obtained in both cases.

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