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Synthesis of 16α,17α-epoxycorticosterone from androsta-4,9-diene-3,17-dione

✍ Scribed by A. M. Turuta; T. M. Fadeeva; M. V. Kamernitskii

Book ID: 112448820
Publisher: Springer
Year: 1991
Tongue: English
Weight: 47 KB
Volume: 40
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00961278

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New Synthesis of Estradiol from Androsta-1,4-diene-3,17-dione. -A new method for the aromatization of ring A in androsta-1,4-diene-3,17-dione (I) via reduction to the corresponding dienediol (II) followed by double C,Odeprotonation of ring A is reported. This two-step transformation of (I) into est