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Synthesis of 1,6-bis(2′-benzimidazolyl)-2,5-dithiahexane and its copper compounds

✍ Scribed by P. J. M. W. L. Birker; J. Helder; J. Reedijk


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
129 KB
Volume
99
Category
Article
ISSN
0165-0513

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✍ Robert L. Soulen; James R. Griffith 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Attempts to homocouple 1,3-bis(2-hydroxyhexafluoro-2-propyl)-5iodobenzene (diol iodide) with copper fail to give the desired biphenyl tetrol. However, the dimethyl ether derivative of the diol iodide reacts smoothly with copper to give the biphenyl tetramethyl ether in good yields. The diacetate der