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Transition-metal coordination compounds of a chelating imidazole-thioether ligand. The molecular structure of diisothiocyanato[1,6-bis(5-methyl-4-imidazolyl)-2,5-dithiahexane]nickel(II)

✍ Scribed by E. Bouwman; R. de Gelder; R. A. G. de Graaff; W. L. Driessen; J. Reedijk

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 409 KB
Volume: 107
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19881070311

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Metal ion induced disintegration of a pyrazole-containing ligand and formation of an unprecedented pyrazolato-bridged di-zinc anion. The X-ray structure of the mixed ligand compound bis [(1,6-bis(3,5-dimethylpyrazol-1-yl)-2,5-dimethyl-2,5-diazahexane)-(chloro)zinc(chloro) zinc(II)] [bis(μ-3,5-dimethylpyrazolato) tetrachlorodizincaat(II)], [Zn(C16H28N6)Cl]2[Zn2(C5H7N2)2Cl4]

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