Synthesis of 1,5-Disubstituted 3-(4-Hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-2-pyrazolines
✍ Scribed by Albert Lévai; József Jekő
- Publisher
- Springer Vienna
- Year
- 2006
- Tongue
- English
- Weight
- 149 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0026-9247
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📜 SIMILAR VOLUMES
The nearly planar molecule of the fungal metabolite infectopyrone, C 14 H 16 O 5 , with an r.m.s. deviation of 0.040 (2) A ˚from the plane through all atoms, is linked tail-to-tail by strong O-HÁ Á ÁO hydrogen bonds into dimers. Weaker C-HÁ Á ÁO hydrogen bonds link the pyran-2-one 'head' groups.
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract 2‐Amino‐6‐(3‐methyl‐5‐oxo‐1‐phenyl‐2‐pyrazolin‐4‐yl)‐4‐phenylpyridine‐3‐carbonitrile (1) obtained by the reaction of 4‐(1‐iminoethyl)‐3‐methyl‐1‐phenyl‐2‐pyrazolin‐5‐one with benzylidenemalononitrile, was reacted with triethyl orthoformate followed by hydrazine hydrate, acetic anhydride