The title compound, C 9 H 12 N 2 O 3 , was synthesized by the reaction in ethanol of ethane-1,2-diamine and 3-[bis(methylthio)methylene]-6-methyl-3,4,5,6-tetrahydro-2H-pyran-2,4dione. Two intramolecular N-HÁ Á ÁO hydrogen bonds induce a high degree of planarity.
5-(4-Methoxy-5-methyl-6-oxo-6H-pyran-2-yl)-3-methylhexa-2,4-dienoic acid
✍ Scribed by Bloor, Stephen J. ;Crump, Douglas R. ;Gainsford, Graeme J.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 307 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The nearly planar molecule of the fungal metabolite infectopyrone, C 14 H 16 O 5 , with an r.m.s. deviation of 0.040 (2) A ˚from the plane through all atoms, is linked tail-to-tail by strong O-HÁ Á ÁO hydrogen bonds into dimers. Weaker C-HÁ Á ÁO hydrogen bonds link the pyran-2-one 'head' groups.
📜 SIMILAR VOLUMES
3-Arylpyrones and 5-arylpyrones featuring the 4-methoxy-2H-pyran-2-one moiety are obtained by Suzuki cross-coupling of the corresponding 3-iodo and 5-bromo derivatives with arylboronic acids.
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.003 A R factor = 0.044 wR factor = 0.125 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.