3-Aryl and 5-aryl-4-methoxy-6-methyl-2H-pyran-2-ones by Suzuki cross-coupling reactions of 3- and 5-halogeno-4-methoxy-6-methyl-2H-pyran-2-ones
✍ Scribed by Silvia Cerezo; Marcial Moreno-Mañas; Roser Pleixats
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 378 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
3-Arylpyrones and 5-arylpyrones featuring the 4-methoxy-2H-pyran-2-one moiety are obtained by Suzuki cross-coupling of the corresponding 3-iodo and 5-bromo derivatives with arylboronic acids.
📜 SIMILAR VOLUMES
The nearly planar molecule of the fungal metabolite infectopyrone, C 14 H 16 O 5 , with an r.m.s. deviation of 0.040 (2) A ˚from the plane through all atoms, is linked tail-to-tail by strong O-HÁ Á ÁO hydrogen bonds into dimers. Weaker C-HÁ Á ÁO hydrogen bonds link the pyran-2-one 'head' groups.
## Abstract The structures of the main products resulting from photocyclodimerization of the title compound **2** and of other 3‐methyl‐substituted ‘oxacyclohex‐2‐en‐1‐ones’ (=dihydropyranones) were determined by X‐ray crystallography. In connection, the ^13^C‐NMR chemical shifts of the cyclobutane